Frank Hauke
Zentralinstitut für Neue Materialien und Prozesstechnik
Sonderforschungsbereich 953 “Synthetic Carbon Allotropes”
Diploma Thesis
Mannich Funktionalisierung von C59N
Ph.D. Thesis
Chemische Funktionalisierung des Heterofulleren-Dimers (C59N)2
Publications
Spatially resolved fluoroalkylation and alkylation of graphene by direct laser writing
In: Chemical Communications (London) 60 (2024), p. 734-737
ISSN: 0009-241X
DOI: 10.1039/D3CC05355E
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Fluorination of antimonene hexagons
In: Chemical Communications (2024)
ISSN: 1359-7345
DOI: 10.1039/d4cc03423f
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Laser-Driven Modular Precision Chemistry of Graphene Using λ3-Iodanes
In: Angewandte Chemie International Edition (2024)
ISSN: 1433-7851
DOI: 10.1002/anie.202414090
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Unconventional conductivity increase in multilayer black phosphorus
In: npj 2D Materials and Applications 7 (2023), Article No.: 21
ISSN: 2397-7132
DOI: 10.1038/s41699-023-00384-2
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Synergistic Combination of Reductive Covalent Functionalization and Atomic Layer Deposition—Towards Spatially Defined Graphene-Organic-Inorganic Heterostructures
In: Angewandte Chemie International Edition (2023)
ISSN: 1433-7851
DOI: 10.1002/anie.202314183
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Spatially Resolved Janus Patterning of Graphene by Direct Laser Writing
In: Journal of the American Chemical Society (2022)
ISSN: 1520-5126
DOI: 10.1021/jacs.2c07280
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Hierarchical Assembly and Sensing Activity of Patterned Graphene-Hamilton Receptor Nanostructures
In: Advanced Materials Interfaces (2022), Article No.: 2200425
ISSN: 2196-7350
DOI: 10.1002/admi.202200425
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Spatial Control of Graphene Functionalization by Patterning a 2D Substrate: Implications for Graphene Based van-der-Waals Heterostructures
In: ACS Applied Nano Materials 5 (2022), p. 4966-4971
ISSN: 2574-0970
DOI: 10.1021/acsanm.1c04559
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Atomically resolved TEM imaging of covalently functionalised graphene
In: npj 2D Materials and Applications 6 (2022)
ISSN: 2397-7132
DOI: 10.1038/s41699-022-00304-w
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Retraction Note: Precise determination of graphene functionalization by in situ Raman spectroscopy
In: Nature Communications 13 (2022), Article No.: 6637
ISSN: 2041-1723
DOI: 10.1038/s41467-022-34281-x
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Molecular Stacking on Graphene
In: Angewandte Chemie International Edition (2022), Article No.: e202201169
ISSN: 1433-7851
DOI: 10.1002/anie.202201169
URL: https://onlinelibrary.wiley.com/doi/epdf/10.1002/anie.202201169
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A straightforward reductive approach for the deoxygenation, activation and functionalization of ultrashort single-walled carbon nanotubes
In: Carbon 171 (2021), p. 768-776
ISSN: 0008-6223
DOI: 10.1016/j.carbon.2020.09.078
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Covalent 2D Patterning, Local Electronic Structure and Polarization Switching of Graphene at the Nanometer Level
In: Chemistry - A European Journal (2021)
ISSN: 0947-6539
DOI: 10.1002/chem.202100941
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Hypervalent Iodine Compounds as Versatile Reagents for Extremely Efficient and Reversible Patterning of Graphene with Nanoscale Precision
In: Advanced Materials (2021), Article No.: 2101653
ISSN: 0935-9648
DOI: 10.1002/adma.202101653
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Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts
In: Chemistry - A European Journal (2021)
ISSN: 0947-6539
DOI: 10.1002/chem.202003584
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Carbon Nano-onions: Potassium Intercalation and Reductive Covalent Functionalization
In: Journal of the American Chemical Society (2021)
ISSN: 1520-5126
DOI: 10.1021/jacs.1c07604
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Evolution of Graphene Patterning: From Dimension Regulation to Molecular Engineering
In: Advanced Materials (2021)
ISSN: 0935-9648
DOI: 10.1002/adma.202104060
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Molecular embroidering of graphene
In: Nature Communications 12 (2021), Article No.: 552
ISSN: 2041-1723
DOI: 10.1038/s41467-020-20651-w
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A general concept for highly efficient covalent laser patterning of graphene based on silver carboxylates
In: Chemical Communications 57 (2021), p. 4654-4657
ISSN: 1359-7345
DOI: 10.1039/d1cc00902h
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Controlling the Formation of Sodium/Black Phosphorus IntercalationCompounds Towards High Sodium Content
In: Batteries & Supercaps (2021)
ISSN: 2566-6223
DOI: 10.1002/batt.202100053
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Fractal-seaweeds type functionalization of graphene
In: Carbon (2020)
ISSN: 0008-6223
DOI: 10.1016/j.carbon.2019.11.008
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Production and processing of graphene and related materials
In: 2D Materials 7 (2020)
ISSN: 2053-1583
DOI: 10.1088/2053-1583/ab1e0a
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Covalently Doped Graphene Superlattices: Spatially Resolved Supratopic- and Janus-Binding
In: Journal of the American Chemical Society 142 (2020), p. 16016-16022
ISSN: 1520-5126
DOI: 10.1021/jacs.0c07173
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Spatially Resolved Bottom-Side Fluorination of Graphene by Two-Dimensional Substrate Patterning
In: Angewandte Chemie International Edition (2020)
ISSN: 1433-7851
DOI: 10.1002/anie.202002508
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Covalent 2D-Engineering of Graphene by Spatially Resolved Laser Writing/Reading/Erasing
In: Angewandte Chemie International Edition (2020)
ISSN: 1433-7851
DOI: 10.1002/anie.202006874
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Understanding the Electron-Doping Mechanism in Potassium-Intercalated Single-Walled Carbon Nanotubes
In: Journal of the American Chemical Society 142 (2020), p. 2327-2337
ISSN: 1520-5126
DOI: 10.1021/jacs.9b11370
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Noncovalent Functionalization and Passivation of Black Phosphorus with Optimized Perylene Diimides for Hybrid Field Effect Transistors
In: Advanced Materials Interfaces (2020)
ISSN: 2196-7350
DOI: 10.1002/admi.202001290
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Ultralong Spin Lifetime in Light Alkali Atom Doped Graphene
In: ACS nano 14 (2020), p. 7492-7501
ISSN: 1936-0851
DOI: 10.1021/acsnano.0c03191
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Tuning Conductivity and Spin Dynamics in Few-Layer Graphene via In Situ Potassium Exposure
In: physica status solidi (b) (2020)
ISSN: 0370-1972
DOI: 10.1002/pssb.202000368
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Mechanical cleaning of graphene using in situ electron microscopy
In: Nature Communications 11 (2020), p. 1743-
ISSN: 2041-1723
DOI: 10.1038/s41467-020-15255-3
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Few-layer Black Phosphorous Catalyzes Radical Additions to Alkenes Faster than Low-valence Metals
In: ChemCatChem (2020)
ISSN: 1867-3880
DOI: 10.1002/cctc.201902276
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Direct Laser Writing on Graphene with Unprecedented Efficiency of Covalent Two-Dimensional Functionalization
In: Journal of the American Chemical Society 142 (2020), p. 21926–21931
ISSN: 1520-5126
DOI: 10.1021/jacs.0c11153
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Recent Advances in Graphene Patterning
In: ChemPlusChem 85 (2020), p. 1655-1668
ISSN: 2192-6506
DOI: 10.1002/cplu.202000419
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Highly Efficient and Reversible Covalent Patterning of Graphene: 2D-Management of Chemical Information
In: Angewandte Chemie International Edition (2020)
ISSN: 1433-7851
DOI: 10.1002/anie.201914088
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Quantifying the Covalent Functionalization of Black Phosphorus
In: Angewandte Chemie International Edition (2020)
ISSN: 1433-7851
DOI: 10.1002/anie.202008646
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Liquid phase exfoliation of carbonate-intercalated layered double hydroxides
In: Chemical Communications 55 (2019), p. 3315-3318
ISSN: 1359-7345
DOI: 10.1039/C9CC00197B
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Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters
In: Nature Communications 10 (2019), Article No.: 509
ISSN: 2041-1723
DOI: 10.1038/s41467-018-08063-3
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A Straightforward Approach to Multifunctional Graphene
In: Chemistry - A European Journal (2019)
ISSN: 0947-6539
DOI: 10.1002/chem.201903165
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Interface Molecular Engineering for Laminated Monolithic Perovskite/Silicon Tandem Solar Cells with 80.4% Fill Factor
In: Advanced Functional Materials 29 (2019), p. 1901476
ISSN: 1616-301X
DOI: 10.1002/adfm.201901476
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Controlling the Degree of Functionalization: In-Depth Quantification and Side-Product Analysis of Diazonium Chemistry on SWCNTs
In: Chemistry - A European Journal (2019)
ISSN: 0947-6539
DOI: 10.1002/chem.201902330
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Reductive diazotation of carbon nanotubes: an experimental and theoretical selectivity study
In: Chemical Science 10 (2019), p. 706-717
ISSN: 2041-6520
DOI: 10.1039/c8sc03737j
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Characterizing the maximum number of layers in chemically exfoliated graphene
In: Scientific Reports 9 (2019), Article No.: 19480
ISSN: 2045-2322
DOI: 10.1038/s41598-019-55784-6
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Exohedral Addition Chemistry of the Fullerenide Anions C602− and C60⋅−
In: Chemistry - A European Journal 25 (2019), p. 5186-5201
ISSN: 0947-6539
DOI: 10.1002/chem.201805777
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Covalent Inter-Synthetic-Carbon-Allotrope Hybrids
In: Accounts of Chemical Research 52 (2019), p. 2037-2045
ISSN: 0001-4842
DOI: 10.1021/acs.accounts.9b00181
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Covalent Inter-Carbon-Allotrope Architectures Consisting of the Endohedral Fullerene Sc3N@C80and Single-Walled Carbon Nanotubes
In: Angewandte Chemie International Edition (2019)
ISSN: 1433-7851
DOI: 10.1002/anie.201902595
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Modular Covalent Graphene Functionalization with C60 and the Endohedral Fullerene Sc3N@C80: A Facile Entry to Synthetic-Carbon-Allotrope Hybrids
In: Angewandte Chemie International Edition 58 (2019), p. 816-820
ISSN: 1433-7851
DOI: 10.1002/anie.201811864
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Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus
In: Angewandte Chemie International Edition 58 (2019), p. 5763-5768
ISSN: 1433-7851
DOI: 10.1002/anie.201811181
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Monolayer black phosphorus by sequential wet-chemical surface oxidation
In: RSC Advances 9 (2019), p. 3570-3576
ISSN: 2046-2069
DOI: 10.1039/c8ra09069f
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Melamine-functionalized graphene oxide: Synthesis, characterization and considering as pseudocapacitor electrode material with intermixed POAP polymer
In: Applied Surface Science 459 (2018), p. 874-883
ISSN: 0169-4332
DOI: 10.1016/j.apsusc.2018.07.215
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Oxo-Functionalized Graphene: A Versatile Precursor for Alkylated Graphene Sheets by Reductive Functionalization
In: Chemistry - A European Journal 24 (2018), p. 13348-13354
ISSN: 0947-6539
DOI: 10.1002/chem.201802500
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Post-Graphene 2D Chemistry: The Emerging Field of Molybdenum Disulfide and Black Phosphorus Functionalization
In: Angewandte Chemie International Edition 57 (2018), p. 4338-4354
ISSN: 1433-7851
DOI: 10.1002/anie.201708211
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Optimized single-layer MoS2 field-effect transistors by non-covalent functionalisation
In: Nanoscale 10 (2018), p. 17557-17566
ISSN: 2040-3364
DOI: 10.1039/c8nr02134a
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Effect of TCNQ Layer Cover on Oxidation Dynamics of Black Phosphorus
In: Physica Status Solidi-Rapid Research Letters 12 (2018), Article No.: ARTN 1800179
ISSN: 1862-6254
DOI: 10.1002/pssr.201800179
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Effect of TCNQ Layer Cover on Oxidation Dynamics of Black Phosphorus
In: Physica Status Solidi-Rapid Research Letters (2018)
ISSN: 1862-6254
DOI: 10.1002/pssr.201800179
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Electronic Properties of Air-Sensitive Nanomaterials Probed with Microwave Impedance Measurements
In: physica status solidi (b) 255 (2018), Article No.: ARTN 1800250
ISSN: 0370-1972
DOI: 10.1002/pssb.201800250
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Isomerically Pure Star-Shaped Triphenylene-Perylene Hybrids Involving Highly Extended π-Conjugation
In: Chemistry - A European Journal 24 (2018), p. 4671-4679
ISSN: 0947-6539
DOI: 10.1002/chem.201705872
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Fundamental Insights into the Reductive Covalent Cross-Linking of Single-Walled Carbon Nanotubes
In: Journal of the American Chemical Society (2018)
ISSN: 0002-7863
DOI: 10.1021/jacs.7b12910
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Fundamental Insights into the Degradation and Stabilization of Thin Layer Black Phosphorus
In: Journal of the American Chemical Society 139 (2017), p. 10432-10440
ISSN: 0002-7863
DOI: 10.1021/jacs.7b04971
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Noncovalent Functionalization and Charge Transfer in Antimonene
In: Angewandte Chemie International Edition 56 (2017), p. 14389-14394
ISSN: 1433-7851
DOI: 10.1002/anie.201702983
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Exploring the Formation of Black Phosphorus Intercalation Compounds with Alkali Metals
In: Angewandte Chemie International Edition 56 (2017), p. 15267-15273
ISSN: 1433-7851
DOI: 10.1002/anie.201707462
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Unifying Principles of the Reductive Covalent Graphene Functionalization
In: Journal of the American Chemical Society 139 (2017), p. 5175-5182
ISSN: 1520-5126
DOI: 10.1021/jacs.7b00704
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Direct Covalent Coupling of Porphyrins to Graphene
In: Journal of the American Chemical Society 139 (2017), p. 11760-11765
ISSN: 1520-5126
DOI: 10.1021/jacs.7b04122
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Selective reduction of SWCNTs-concepts and insights
In: Journal of Materials Chemistry C 5 (2017), p. 3937-3947
ISSN: 2050-7526
DOI: 10.1039/c5tc01407g
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Highly Regioselective Alkylation of Hexabenzocoronenes: Fundamental Insights into the Covalent Chemistry of Graphene
In: Angewandte Chemie International Edition 56 (2017), p. 12184-12190
ISSN: 1433-7851
DOI: 10.1002/anie.201706437
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Reductive Functionalization of Graphenides With Nickel(II) Porphyrin Diazonium Compounds
In: Physica Status Solidi-Rapid Research Letters 11 (2017), Article No.: 1700306
ISSN: 1862-6254
DOI: 10.1002/pssr.201700306
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Diameter dependence of the defect-induced Raman modes in functionalized carbon nanotubes
In: Carbon 112 (2017), p. 1-7
ISSN: 0008-6223
DOI: 10.1016/j.carbon.2016.10.065
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Perylene-based non-covalent functionalization of 2D materials
In: FlatChem 1 (2017), p. 89-103
ISSN: 2452-2627
DOI: 10.1016/j.flatc.2017.01.001
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Electronic and Magnetic Properties of Black Phosphorus
In: physica status solidi (b) 254 (2017), Article No.: 1700232
ISSN: 0370-1972
DOI: 10.1002/pssb.201700232
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Precise determination of graphene functionalization by in situ Raman spectroscopy
In: Nature Communications 8 (2017), Article No.: 15192
ISSN: 2041-1723
DOI: 10.1038/ncomms15192
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Degree of functionalisation dependence of individual Raman intensities in covalent graphene derivatives
In: Scientific Reports 7 (2017)
ISSN: 2045-2322
DOI: 10.1038/srep45165
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Noncovalent Functionalization of Black Phosphorus
In: Angewandte Chemie-International Edition 55 (2016), p. 14557 –14562
ISSN: 1433-7851
DOI: 10.1002/anie.201604784
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Alkoxide-intercalated NiFe-layered double hydroxides magnetic nanosheets as efficient water oxidation electrocatalysts
In: Inorganic Chemistry Frontiers 3 (2016), p. 478-487
ISSN: 2052-1553
DOI: 10.1039/c6qi00009f
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Few-Layer Antimonene by Liquid-Phase Exfoliation
In: Angewandte Chemie International Edition 55 (2016), p. 14345-14349
ISSN: 1433-7851
DOI: 10.1002/anie.201605298
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Topology-Driven Reductive Silylation of Synthetic Carbon Allotropes
In: Journal of the American Chemical Society 138 (2016), p. 15642-15647
ISSN: 1520-5126
DOI: 10.1021/jacs.6b09487
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Mono- and Ditopic Bisfunctionalization of Graphene
In: Angewandte Chemie International Edition 55 (2016), p. 5861-5864
ISSN: 1433-7851
DOI: 10.1002/anie.201511807
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Highly Integrated Organic–Inorganic Hybrid Architectures by Noncovalent Exfoliation of Graphite and Assembly with Zinc Oxide Nanoparticles
In: Advanced Materials Interfaces 3 (2016), Article No.: 1600365
ISSN: 2196-7350
DOI: 10.1002/admi.201600365
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Basic Insights into Tunable Graphene Hydrogenation
In: Journal of the American Chemical Society 138 (2016), p. 1647-52
ISSN: 1520-5126
DOI: 10.1021/jacs.5b11994
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Substrate-Modulated Reductive Graphene Functionalization
In: Angewandte Chemie International Edition 55 (2016), p. 14858-14862
ISSN: 1433-7851
DOI: 10.1002/anie.201607427
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Solvent-driven electron trapping and mass transport in reduced graphites to access perfect graphene
In: Nature Communications 7 (2016), Article No.: 12411
ISSN: 2041-1723
DOI: 10.1038/ncomms12411
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Naphthalenebisimides as photofunctional surfactants for SWCNTs - towards water-soluble electron donor-acceptor hybrids
In: Chemical Science 6 (2015), p. 6886-6895
ISSN: 2041-6520
DOI: 10.1039/c5sc02944a
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Liquid exfoliation of solvent-stabilized few-layer black phosphorus for applications beyond electronics
In: Nature Communications 6 (2015), Article No.: 8563
ISSN: 2041-1723
DOI: 10.1038/ncomms9563
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Basal-Plane Functionalization of Chemically Exfoliated Molybdenum Disulfide by Diazonium Salts
In: ACS nano 9 (2015), p. 6018-6030
ISSN: 1936-0851
DOI: 10.1021/acsnano.5b00965
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Transport, magnetic and vibrational properties of chemically exfoliated few-layer graphene
In: physica status solidi (b) 252 (2015), p. 2438-2443
ISSN: 0370-1972
DOI: 10.1002/pssb.201552296
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Polyhydrogenated Graphene: Excited State Dynamics in Photo- and Electroactive Two-Dimensional Domains
In: Journal of the American Chemical Society 137 (2015), p. 13079-13086
ISSN: 0002-7863
DOI: 10.1021/jacs.5b07896
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A supramolecular approach for the facile solubilization and separation of covalently functionalized single-walled carbon nanotubes
In: Chemistry - A European Journal 20 (2014), p. 2537-2541
ISSN: 0947-6539
DOI: 10.1002/chem.201303506
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Brominated single walled carbon nanotubes as versatile precursors for covalent sidewall functionalization
In: Chemical Communications 50 (2014), p. 6582-6584
ISSN: 1359-7345
DOI: 10.1039/c4cc00719k
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Novel λ(3)-iodane-based functionalization of synthetic carbon allotropes (SCAs)-common concepts and quantification of the degree of addition
In: Chemistry - A European Journal 20 (2014), p. 16644-16651
ISSN: 0947-6539
DOI: 10.1002/chem.201404662
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Novel EDTA-ligands containing an integral perylene bisimide (PBI) core as an optical reporter unit
In: Organic & Biomolecular Chemistry 12 (2014), p. 7045-7058
ISSN: 1477-0520
DOI: 10.1039/c4ob01007h
, , , , :
Reductive arylation of graphene: Insights into a reversible carbon allotrope functionalization reaction
In: physica status solidi (b) 251 (2014), p. 2536-2540
ISSN: 0370-1972
DOI: 10.1002/pssb.201451315
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Tuning the adsorption of perylene-based surfactants on the surface of single-walled carbon nanotubes
In: physica status solidi (b) 250 (2013), p. 2592-2598
ISSN: 0370-1972
DOI: 10.1002/pssb.201300109
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Scanning-Raman-microscopy for the statistical analysis of covalently functionalized graphene
In: Acs Nano 7 (2013), p. 5472-5482
ISSN: 1936-0851
DOI: 10.1021/nn401481h
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Wet chemical functionalization of graphene
In: Accounts of Chemical Research 46 (2013), p. 87-96
ISSN: 0001-4842
DOI: 10.1021/ar300116q
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New basic insight into reductive functionalization sequences of single walled carbon nanotubes (SWCNTs)
In: Journal of the American Chemical Society 135 (2013), p. 18385-18395
ISSN: 0002-7863
DOI: 10.1021/ja4063713
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Mapping charge transport by electroluminescence in chirality-selected carbon nanotube networks
In: Acs Nano 7 (2013), p. 7428-7435
ISSN: 1936-0851
DOI: 10.1021/nn403419d
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Screening of the chemical reactivity of three different graphite sources using the formation of reductively alkylated graphene as a model reaction
In: Chemical Communications 49 (2013), p. 10811-10813
ISSN: 1359-7345
DOI: 10.1039/c3cc46621c
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Raman bands of nano-graphene flakes on carbon nanotubes after oxidation
In: physica status solidi (b) 250 (2013), p. 2687-2691
ISSN: 0370-1972
DOI: 10.1002/pssb.201300224
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On the way to graphane - Pronounced fluorescence of polyhydrogenated graphene
In: Angewandte Chemie International Edition 52 (2013), p. 754-757
ISSN: 1433-7851
DOI: 10.1002/anie.201206799
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Region-Selective Self-Assembly of Functionalized Carbon Allotropes from Solution
In: Acs Nano 7 (2013), p. 11427-11434
ISSN: 1936-0851
DOI: 10.1021/nn405488n
URL: http://pubs.acs.org/doi/abs/10.1021/nn405488n
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Functionalization of graphene by electrophilic alkylation of reduced graphite
In: Chemical Communications 48 (2012), p. 5025-5027
ISSN: 1359-7345
DOI: 10.1039/c2cc31181j
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Statistical raman spectroscopy: An method for the characterization of covalently functionalized single-walled carbon nanotubes
In: Angewandte Chemie International Edition 51 (2012), p. 11727-11730
ISSN: 1433-7851
DOI: 10.1002/anie.201204791
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Effect of polymer molecular weight and solution parameters on selective dispersion of single-walled carbon nanotubes
In: ACS Macro Letters 1 (2012), p. 815-819
ISSN: 2161-1653
DOI: 10.1021/mz300147g
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Density gradient ultracentrifugation on carbon nanotubes according to structural integrity as a foundation for an absolute purity evaluation
In: ChemPhysChem 12 (2011), p. 2576-2580
ISSN: 1439-4235
DOI: 10.1002/cphc.201100258
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The potential of perylene bisimide derivatives for the solubilization of carbon nanotubes and graphene
In: Advanced Materials 23 (2011), p. 2588-2601
ISSN: 0935-9648
DOI: 10.1002/adma.201100300
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Perylene-based nanotweezers: Enrichment of larger-diameter single-walled carbon nanotubes
In: Chemistry-An Asian Journal 6 (2011), p. 438-444
ISSN: 1861-4728
DOI: 10.1002/asia.201000647
, , , :
Counterion effect on the aggregation of anionic perylene dyes and the influence on carbon nanotube dispersion efficiencies
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